Abstract: From a new perspective of the enterprise value theory, combining the current interest and the long-term benefit and integrating the short-term goal and the long-term development, the index system was built to evaluate the performance of enterprise's green supply chain, which includes the primary indicator of enterprise's profit ability, growth ability, ability to resist risk, sustainable development and green environmental protection and 22 secondary indicators. Considering the green supply chain performance evaluation as the multi-criteria decision problem, analytic network process (ANP) was used to evaluate the performance, and super decisions (SD) software to calculate it's weights.