多环芳烃在黑土有机-矿质复合体中的老化行为

Aging Behaviour of Polycyclic Aromatic Hydrocarbons in Organo-Mineral Aggregates from Black Soil

  • 摘要: 研究多环芳烃菲和蒽在黑土不同粒径有机-矿质复合体中的老化现象,采用二氯甲烷提取法测定老化后多环芳烃菲和蒽的可提取性,比较不同粒径有机-矿质复合体中老化的速率.实验结果表明,老化90 d后,菲的可提取率下降10%,蒽的可提取率下降30%,粘粒级复合体中最初阶段(0<sup<1</sup<5 d)的老化速率最高,其余粒径复合体老化速率最高阶段基本都在15<sup<2</sup<8 d.

     

    Abstract: Aging behaviour of polycyclic aromatic hydrocarbons(PAHs) phenanthrene and anthracene in organo-mineral aggregates from black soil were studied under laboratory incubation.Changes in their extractability and aging rate in different fractions of organo-mineral aggregates were determined through extraction by dichloromethane.After incubation for 90 days,the extractability of phenanthrene and anthracene were seen to be decreased about 10% and 30%,respectively.In clay fractions,the aging rate in the first period(from 0 to 15 days) appeared highest,while in the other three fractions,the higher aging rates existed basically in the period from 15 to 28 days.

     

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