陶瓷厚膜无机电致发光显示器中ZnS∶Mn发光层的优化制备

Optimal Fabrication of ZnS∶Mn Phosphor Layer in Inorganic Thick Dielectric Electroluminescent Displays

  • 摘要: 为了提高陶瓷厚膜无机电致发光显示器的亮度,采用陶瓷基片/内电极/陶瓷厚膜/发光层/上绝缘层/透明电极的器件结构系统研究了ZnS∶Mn发光层的制备工艺.结果表明当优化的发光层厚度为600 nm,沉积温度为280℃时制备ZnS∶Mn发光层可以获得器件的最大亮度.在高温500℃退火时,器件的亮度-驱动电压曲线最优.发光层结晶性的改善和Mn+的均匀扩散,使得优化的沉积温度和退火温度制备的ZnS∶Mn发光层具有良好的光电特性.

     

    Abstract: Based on the structure of ceramic substrate/internal electrodes/thick dielectric film/light-emitting layer/thin dielectric film/ITO,the fabrication process of ZnS:Mn phosphor layer has been investigated to improve the brightness of inorganic thick dielectric electroluminescent(TDEL) devices.The optimal thickness and fabrication temperature of ZnS∶Mn film are 600?nm and 280?℃,respectively,and produced the highest brightness of TDEL devices.The photoelectric properties of TDEL devices were improved by an annealing process of ZnS∶Mn layer,and the optimal brightness-voltage curve(that is,the biggest brightness and the steepest curve) of TDEL devices was obtained by an annealing temperature of 500?℃.The improvement of photoelectric properties of TDEL devices by the optimal fabrication temperature and annealing temperature of ZnS∶Mn layer was attributed to the crystalline improvement of ZnS∶Mn layer and the uniform diffusion of Mn+.

     

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