C60-γ-氨丙基硅胶的合成与表征

Synthesis of C60-γ-Aminopropylsilyl-Bonded Silica

  • 摘要: 采用γ-氨丙基-三乙氧基硅烷作为偶联剂,将伯胺基引入到硅胶上,随后让C60与伯胺基反应,合成了C60-γ-氨丙基硅胶.利用元素分析法和Esko等描述的游离伯胺基含量测定方法,分别测得每1g硅胶中C60的键合量为1.19×10-5mol和1.09×10-5mol.

     

    Abstract: C60 γ aminopropylsilyl bonded silica was synthesized by chemical attachment of γ aminopropylsilyl to silica, followed by the reaction of C60 with alkylamine. Using elemental analysis and the method for measuring the amounts of alkylamine described by Esko et al., the content of bonded C60 was determined to be 1 19×10 -5 mol and 1 09×10 -5 mol in per gram silica, respectively.

     

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