C60-γ-氨丙基硅胶的合成与表征
Synthesis of C60-γ-Aminopropylsilyl-Bonded Silica
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摘要: 采用γ-氨丙基-三乙氧基硅烷作为偶联剂,将伯胺基引入到硅胶上,随后让C60与伯胺基反应,合成了C60-γ-氨丙基硅胶.利用元素分析法和Esko等描述的游离伯胺基含量测定方法,分别测得每1g硅胶中C60的键合量为1.19×10-5mol和1.09×10-5mol.Abstract: C60 γ aminopropylsilyl bonded silica was synthesized by chemical attachment of γ aminopropylsilyl to silica, followed by the reaction of C60 with alkylamine. Using elemental analysis and the method for measuring the amounts of alkylamine described by Esko et al., the content of bonded C60 was determined to be 1 19×10 -5 mol and 1 09×10 -5 mol in per gram silica, respectively.
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