N,N'—双(2,4,6—三硝基—3,5—二氨基苯基)—3,5—二硝基—2,6—二氨基吡啶的合成

Synthesis of N, N''''-Bis(2, 4, 6-Trinitro-3, 5-Diaminophenyl)-3, 5-Dinitro-2, 6 -Diaminopyridine

  • 摘要: 为了寻找热稳定性与美国LosAlamos国家实验室合成的2,6-二苦胺基-3,5-二硝基吡啶(代号PYX)相当,晶体密度等性能优于PYX的新型含能材料,将2,6-二氨基吡啶与三硝基三氯苯缩合,然后通过硝化和氨化反应,合成了晶体密度、感度、爆速均优于PYX的题称化合物,并对有关理论问题作了讨论.

     

    Abstract: In order to explore new energetic materials having a thermal stability compara comparable to that of PYX yet with a higher CryStal densidensity PYX as synthesized in the Los Alamos National Laboratory, the title compound which has a higher crystal density and lower impact sensitivity and higher detonation velocity has ho synthesized through a succession of condensation, nitration, and ammoniation reactions. Some of the theoretical analyses concerning the compound are given.

     

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