偕-双(丙基二茂铁基)烷烃燃速催化剂的研究

Synthesis of Bis (Propylferrocenyl) Alkanes and Their Use as Combustion Catalysts

摘要: 合成和表征了三种新型燃速催化剂:偕-双(丙基二茂铁基)甲烷,2,2-双(丙基二茂铁基)丙烷和2,2一双(丙基二茂铁基)丁烷,研究了上述化合物和偕-双(甲基及乙基二茂铁基)烷烃衍生物的电化学性能,探讨取代基和偶联基团对其催化性能的影响,对它们的迁移性与国内目前常用的叔丁基二茂铁(TBF)做了比较试验。

Abstract: Three propylferrocene derivatives have been synthsized :bis(propylferro -cenyl) methane , 2 ,2 - bis (propylferrocenyl) propane , and 2,2 - bis (propylferro -cenyl) butane . The electrochemical potential , combustion catalytic activity and emigration of the synthesized compounds as well as those of the methylferrocene , and ethylferrocene derivatives , were studied .